The third match on Center Court has the Murrays taking on the Australian duo of John Peers and Rinky Hijikata.
The 32nd-seeded Katie Boulter will play Harriet Dart in the second round of the singles, while the top-seeded Jack Draper of the United Kingdom will play Cameron Norrie, the 2022 semifinalist.
Playing first on center court, British wildcard and recent college graduate Jacob Fearnley faces seven-time champion Novak Djokovic.
When Lily Miyazaki faces 14th seed Daria Kasatkina on court 18 at 11:00 BST, she hopes to advance to the third round alongside Emma Raducanu and Sonay Kartal.
However, he has declared himself well enough to play a heartfelt role in the men’s doubles alongside his older brother Jamie, barely ten days after undergoing back surgery.
Despite their memorable partnership during Great Britain’s 2015 Davis Cup victory and their participation in the men’s doubles at three Olympics Games, including London 2012, the two have never played together at the Championships.